BINAM-prolinamides are very efficient catalyst for the synthesis of non-protected and N-benzyl isatin derivatives by using an aldol reaction between ketones and isatins under solvent-free conditions. The results in terms of diastereo- and enantioselectivities are good, up to 99% de and 97% ee, and higher to those previously reported in the literature under similar reaction conditions. A high va...

quantitative valuations of observed heterosis for 11 traits of 15 f1 hybrids generated by half diallel crosses of six diverse rice cultivars (domsefid, hashemi and binam, three iranian local cultivars; dorfak, kadous and ir30, three improved cultivars), were made in this study. fifteen f1 hybrids and their parents were evaluated in a randomized complete block design with three replications at t...

(S(a))-Binam-D-prolinamide (20 mol%), instead of (S(a))-binam-L-prolinamide, in combination with chloroacetic acid (100 mol%) is an efficient organocatalyst for the direct aldol reaction between α-keto esters as electrophiles and alkyl and α-functionalised ketones, under quasi solvent-free conditions, providing access to highly functionalised chiral quaternary γ-keto α-hydroxyesters with up to ...

A study was carried out at the Rice Research Institute of Iran (RRII) to investigate the effect of rollers differential peripheral speed of commercial rubber roll husker and paddy moisture content on the husking index and percentage of broken rice. The experiment was conducted at six levels of rollers differential speed (1.5, 2.2, 2.9, 3.6, 4.3 and 5 m/s) and three levels of paddy moisture cont...

The dual activation of acyl phosphonates and formaldehyde tert-butyl hydrazone by a BINAM-derived bis-urea catalyst is the key to achieve high reactivities and enantioselectivities in the synthesis of densely functionalized quaternary α-hydroxy phosphonates. Subsequent high-yielding transformations in a 'one-pot' fashion provide direct access to valuable azoxy compounds and quaternary α-aryl-ph...

to estimate combining ability and the model of gene action for some quantitative characters, 5 different rice genotypes were used for producing a half diallel hybrids. to consider 7 quantitative traits, hybrids and their corresponding parents were evaluated based on a randomized complete block design with three replications at the rice research station of amol, iran in 2007. mean squares regard...

to identify qtls controlling grain yield and yield components, an f2 population consisting of 188 plants derived from the cross between two rice pure lines, binam and kadous, were grown in research field of faculty of agricultural sciences, university of guilan, rasht, iran, in 2008, and were recorded for 9 important traits related to grain yield. to construct linkage map, 85 marker of ssrs and...

A facile and moderately functional-group-tolerant synthetic method for the preparation of 7,8-diaza[5]helicenes has been developed. It comprises of an oxidative ring-closing process of 1,1'-binaphthalene-2,2'-diamine (BINAM) derivatives with a chlorine-containing oxidant (t-BuOCl) in the presence of a base (2,6-lutidine). In addition the basic physicochemical properties of newly synthesized com...

The facile and green synthesis of 1,1′-binaphthalene-2,2′-diamine (BINAM) derivatives was established via the anodic dehydrogenative homo-coupling 2-naphthylamines. sustainable protocol provided a series BINAMs in excellent yields up to 98% with good current efficiency (66%) H2 as sole coproduct without utilizing transition-metal reagents or stoichiometric oxidants.